A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and n-n Interactions, {[Zn(phen)2(H2O) {Ag(CN)2}][Ag(CN)2] MeOH}n (phen = 1,10-Phenanthroline)

Muhammad Monim-ul-Mehboob; Muhammad Ramzan; Tobias Rüffer; Heinrich Lang; Shafqat Naddem; Muhammad Akhtar; Saeed Ahmad

doi:10.5560/znb.2013-2253

A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and n-n Interactions, {[Zn(phen)₂(H₂O) {Ag(CN)₂}][Ag(CN)₂] MeOH}_n (phen = 1,10-Phenanthroline)

Muhammad Monim-ul-Mehboob
, Muhammad Ramzan
, Tobias Rüffer
, Heinrich Lang
, Shafqat Naddem
, Muhammad Akhtar
, Saeed Ahmad

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A cyanido-bridged Zn(II)-Ag(I) bimetallic coordination polymer, {[Zn(phen)₂(H₂O){Ag(CN)₂}][Ag(CN)₂]-MeOH}., (1), was prepared using ZnCl2, 1,10-phenanthroline (phen) and K[Ag(CN)₂] and characterized by IR spectroscopy, thermal analysis and X-ray crystallography. The crystal structure of 1 consists of dinuclear [Zn(phen)₂(H₂O){Ag(CN)₂}]⁺ cations, [Ag(CN)₂]^- anions and a methanol molecule. The non-coordinated [Ag(CN)₂]^- anions are linked to the [Zn(phen)₂(H₂O){Ag(CN)₂}]₊ complex cations through argentophilic interactions leading to the formation of chains. The chains are connected by hydrogen bonds and n-n interactions to give a 3D network.

Original language	English
Pages (from-to)	161-167
Number of pages	7
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	68
Issue number	2
DOIs	https://doi.org/10.5560/znb.2013-2253
State	Published - Feb 2013
Externally published	Yes

Keywords

1,10-Phenanthroline
Coordination Polymer
Silver Cyanide
Zinc(II)

ASJC Scopus subject areas

General Chemistry

Access to Document

10.5560/znb.2013-2253

Cite this

Monim-ul-Mehboob, M., Ramzan, M., Rüffer, T., Lang, H., Naddem, S., Akhtar, M., & Ahmad, S. (2013). A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and n-n Interactions, {[Zn(phen)₂(H₂O) {Ag(CN)₂}][Ag(CN)₂] MeOH}_n (phen = 1,10-Phenanthroline). Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 68(2), 161-167. https://doi.org/10.5560/znb.2013-2253

@article{ab415fd40c0a46c9b78ae6a8a67352b6,

title = "A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and n-n Interactions, \{[Zn(phen)2(H2O) \{Ag(CN)2\}][Ag(CN)2] MeOH\}n (phen = 1,10-Phenanthroline)",

abstract = "A cyanido-bridged Zn(II)-Ag(I) bimetallic coordination polymer, \{[Zn(phen)2(H2O)\{Ag(CN)2\}][Ag(CN)2]-MeOH\}., (1), was prepared using ZnCl2, 1,10-phenanthroline (phen) and K[Ag(CN)2] and characterized by IR spectroscopy, thermal analysis and X-ray crystallography. The crystal structure of 1 consists of dinuclear [Zn(phen)2(H2O)\{Ag(CN)2\}]+ cations, [Ag(CN)2]- anions and a methanol molecule. The non-coordinated [Ag(CN)2]- anions are linked to the [Zn(phen)2(H2O)\{Ag(CN)2\}]+ complex cations through argentophilic interactions leading to the formation of chains. The chains are connected by hydrogen bonds and n-n interactions to give a 3D network.",

keywords = "1,10-Phenanthroline, Coordination Polymer, Silver Cyanide, Zinc(II)",

author = "Muhammad Monim-ul-Mehboob and Muhammad Ramzan and Tobias R{\"u}ffer and Heinrich Lang and Shafqat Naddem and Muhammad Akhtar and Saeed Ahmad",

year = "2013",

month = feb,

doi = "10.5560/znb.2013-2253",

language = "English",

volume = "68",

pages = "161--167",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "2",

}

Monim-ul-Mehboob, M, Ramzan, M, Rüffer, T, Lang, H, Naddem, S, Akhtar, M & Ahmad, S 2013, 'A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and n-n Interactions, {[Zn(phen)₂(H₂O) {Ag(CN)₂}][Ag(CN)₂] MeOH}_n (phen = 1,10-Phenanthroline)', Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, vol. 68, no. 2, pp. 161-167. https://doi.org/10.5560/znb.2013-2253

A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and n-n Interactions, {[Zn(phen)₂(H₂O) {Ag(CN)₂}][Ag(CN)₂] MeOH}_n (phen = 1,10-Phenanthroline). / Monim-ul-Mehboob, Muhammad; Ramzan, Muhammad; Rüffer, Tobias et al.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 68, No. 2, 02.2013, p. 161-167.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and n-n Interactions, {[Zn(phen)2(H2O) {Ag(CN)2}][Ag(CN)2] MeOH}n (phen = 1,10-Phenanthroline)

AU - Monim-ul-Mehboob, Muhammad

AU - Ramzan, Muhammad

AU - Rüffer, Tobias

AU - Lang, Heinrich

AU - Naddem, Shafqat

AU - Akhtar, Muhammad

AU - Ahmad, Saeed

PY - 2013/2

Y1 - 2013/2

N2 - A cyanido-bridged Zn(II)-Ag(I) bimetallic coordination polymer, {[Zn(phen)2(H2O){Ag(CN)2}][Ag(CN)2]-MeOH}., (1), was prepared using ZnCl2, 1,10-phenanthroline (phen) and K[Ag(CN)2] and characterized by IR spectroscopy, thermal analysis and X-ray crystallography. The crystal structure of 1 consists of dinuclear [Zn(phen)2(H2O){Ag(CN)2}]+ cations, [Ag(CN)2]- anions and a methanol molecule. The non-coordinated [Ag(CN)2]- anions are linked to the [Zn(phen)2(H2O){Ag(CN)2}]+ complex cations through argentophilic interactions leading to the formation of chains. The chains are connected by hydrogen bonds and n-n interactions to give a 3D network.

AB - A cyanido-bridged Zn(II)-Ag(I) bimetallic coordination polymer, {[Zn(phen)2(H2O){Ag(CN)2}][Ag(CN)2]-MeOH}., (1), was prepared using ZnCl2, 1,10-phenanthroline (phen) and K[Ag(CN)2] and characterized by IR spectroscopy, thermal analysis and X-ray crystallography. The crystal structure of 1 consists of dinuclear [Zn(phen)2(H2O){Ag(CN)2}]+ cations, [Ag(CN)2]- anions and a methanol molecule. The non-coordinated [Ag(CN)2]- anions are linked to the [Zn(phen)2(H2O){Ag(CN)2}]+ complex cations through argentophilic interactions leading to the formation of chains. The chains are connected by hydrogen bonds and n-n interactions to give a 3D network.

KW - 1,10-Phenanthroline

KW - Coordination Polymer

KW - Silver Cyanide

KW - Zinc(II)

UR - https://www.scopus.com/pages/publications/84874871499

U2 - 10.5560/znb.2013-2253

DO - 10.5560/znb.2013-2253

M3 - Article

AN - SCOPUS:84874871499

SN - 0932-0776

VL - 68

SP - 161

EP - 167

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 2

ER -

Monim-ul-Mehboob M, Ramzan M, Rüffer T, Lang H, Naddem S, Akhtar M et al. A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and n-n Interactions, {[Zn(phen)₂(H₂O) {Ag(CN)₂}][Ag(CN)₂] MeOH}_n (phen = 1,10-Phenanthroline). Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2013 Feb;68(2):161-167. doi: 10.5560/znb.2013-2253