A solid phase extraction procedure for Indium prior to its graphite furnace atomic absorption spectrometric determination

Mustafa Tuzen; Mustafa Soylak

doi:10.1016/j.jhazmat.2005.08.031

A solid phase extraction procedure for Indium prior to its graphite furnace atomic absorption spectrometric determination

Mustafa Tuzen, Mustafa Soylak^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

A procedure based on solid phase extraction of indium ions at trace level on Chromosorb 108 resin as bathocuproinedisulfonic acid chelate is presented for its preconcentration. The optimum pH value for quantitative sorption is 8.0-9.0, and desorption can be achieved by using 10.0 ml of 2 M HNO₃. The effects of diverse ions on the sorption and recovery of indium have been studied. The capacity of sorbent was 3.78 mg In/g resin. Recoveries for indium from water samples were in the range 95-105%. The accuracy of procedure was confirmed by indium determination in certified reference materials. The method developed was applied with varying results to the analysis of real samples including metallic zinc with satisfactory results.

Original language	English
Pages (from-to)	179-185
Number of pages	7
Journal	Journal of Hazardous Materials
Volume	129
Issue number	1-3
DOIs	https://doi.org/10.1016/j.jhazmat.2005.08.031
State	Published - 28 Feb 2006
Externally published	Yes

Bibliographical note

Funding Information:
Dr. Mustafa Soylak would like to thank the Scientific and Technical Research Council of Turkey (TUBITAK) for financial helps (Project No: TBAG-AY/408 (105T010)).

Keywords

Bathocuproinedisulfonic acid
Chromosorb 108
GFAAS
Indium
Metallic zinc
Preconcentration

ASJC Scopus subject areas

Environmental Engineering
Environmental Chemistry
Waste Management and Disposal
Pollution
Health, Toxicology and Mutagenesis

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10.1016/j.jhazmat.2005.08.031

Cite this

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title = "A solid phase extraction procedure for Indium prior to its graphite furnace atomic absorption spectrometric determination",

abstract = "A procedure based on solid phase extraction of indium ions at trace level on Chromosorb 108 resin as bathocuproinedisulfonic acid chelate is presented for its preconcentration. The optimum pH value for quantitative sorption is 8.0-9.0, and desorption can be achieved by using 10.0 ml of 2 M HNO3. The effects of diverse ions on the sorption and recovery of indium have been studied. The capacity of sorbent was 3.78 mg In/g resin. Recoveries for indium from water samples were in the range 95-105\%. The accuracy of procedure was confirmed by indium determination in certified reference materials. The method developed was applied with varying results to the analysis of real samples including metallic zinc with satisfactory results.",

keywords = "Bathocuproinedisulfonic acid, Chromosorb 108, GFAAS, Indium, Metallic zinc, Preconcentration",

author = "Mustafa Tuzen and Mustafa Soylak",

note = "Funding Information: Dr. Mustafa Soylak would like to thank the Scientific and Technical Research Council of Turkey (TUBITAK) for financial helps (Project No: TBAG-AY/408 (105T010)).",

year = "2006",

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doi = "10.1016/j.jhazmat.2005.08.031",

language = "English",

volume = "129",

pages = "179--185",

journal = "Journal of Hazardous Materials",

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number = "1-3",

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TY - JOUR

T1 - A solid phase extraction procedure for Indium prior to its graphite furnace atomic absorption spectrometric determination

AU - Tuzen, Mustafa

AU - Soylak, Mustafa

N1 - Funding Information: Dr. Mustafa Soylak would like to thank the Scientific and Technical Research Council of Turkey (TUBITAK) for financial helps (Project No: TBAG-AY/408 (105T010)).

PY - 2006/2/28

Y1 - 2006/2/28

N2 - A procedure based on solid phase extraction of indium ions at trace level on Chromosorb 108 resin as bathocuproinedisulfonic acid chelate is presented for its preconcentration. The optimum pH value for quantitative sorption is 8.0-9.0, and desorption can be achieved by using 10.0 ml of 2 M HNO3. The effects of diverse ions on the sorption and recovery of indium have been studied. The capacity of sorbent was 3.78 mg In/g resin. Recoveries for indium from water samples were in the range 95-105%. The accuracy of procedure was confirmed by indium determination in certified reference materials. The method developed was applied with varying results to the analysis of real samples including metallic zinc with satisfactory results.

AB - A procedure based on solid phase extraction of indium ions at trace level on Chromosorb 108 resin as bathocuproinedisulfonic acid chelate is presented for its preconcentration. The optimum pH value for quantitative sorption is 8.0-9.0, and desorption can be achieved by using 10.0 ml of 2 M HNO3. The effects of diverse ions on the sorption and recovery of indium have been studied. The capacity of sorbent was 3.78 mg In/g resin. Recoveries for indium from water samples were in the range 95-105%. The accuracy of procedure was confirmed by indium determination in certified reference materials. The method developed was applied with varying results to the analysis of real samples including metallic zinc with satisfactory results.

KW - Bathocuproinedisulfonic acid

KW - Chromosorb 108

KW - GFAAS

KW - Indium

KW - Metallic zinc

KW - Preconcentration

UR - https://www.scopus.com/pages/publications/33644508932

U2 - 10.1016/j.jhazmat.2005.08.031

DO - 10.1016/j.jhazmat.2005.08.031

M3 - Article

C2 - 16202517

AN - SCOPUS:33644508932

SN - 0304-3894

VL - 129

SP - 179

EP - 185

JO - Journal of Hazardous Materials

JF - Journal of Hazardous Materials

IS - 1-3

ER -

A solid phase extraction procedure for Indium prior to its graphite furnace atomic absorption spectrometric determination

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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