A novel Rh-PCy3-CO-HCOOH catalytic system for the regioselective conversion of alkenes to aldehydes

Bassam El Ali; Giuseppe Vasapollo; Howard Alper

doi:10.1016/1381-1169(96)00070-2

A novel Rh-PCy₃-CO-HCOOH catalytic system for the regioselective conversion of alkenes to aldehydes

Bassam El Ali, Giuseppe Vasapollo, Howard Alper^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Rhodium carbonyl and tricyclohexylphosphine, in the presence of CO and HCOOH, is an efficient catalytic system for the regioselective conversion of alkenes into branched and linear aldehydes. This process shows excellent functional group tolerance.

Original language	English
Pages (from-to)	195-201
Number of pages	7
Journal	Journal of Molecular Catalysis A: Chemical
Volume	112
Issue number	2
DOIs	https://doi.org/10.1016/1381-1169(96)00070-2
State	Published - 25 Oct 1996
Externally published	Yes

Bibliographical note

Funding Information:
We are grateful to the Natural Sciences and Engineering Research Council of Canada, for support of this research.

Keywords

Aldehydes
Alkene conversion
Carbon monoxide
Formic acid
Regioselectivity
Rhodium

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

Access to Document

10.1016/1381-1169(96)00070-2

Cite this

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title = "A novel Rh-PCy3-CO-HCOOH catalytic system for the regioselective conversion of alkenes to aldehydes",

abstract = "Rhodium carbonyl and tricyclohexylphosphine, in the presence of CO and HCOOH, is an efficient catalytic system for the regioselective conversion of alkenes into branched and linear aldehydes. This process shows excellent functional group tolerance.",

keywords = "Aldehydes, Alkene conversion, Carbon monoxide, Formic acid, Regioselectivity, Rhodium",

author = "{El Ali}, Bassam and Giuseppe Vasapollo and Howard Alper",

note = "Funding Information: We are grateful to the Natural Sciences and Engineering Research Council of Canada, for support of this research.",

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AU - El Ali, Bassam

AU - Vasapollo, Giuseppe

AU - Alper, Howard

N1 - Funding Information: We are grateful to the Natural Sciences and Engineering Research Council of Canada, for support of this research.

PY - 1996/10/25

Y1 - 1996/10/25

N2 - Rhodium carbonyl and tricyclohexylphosphine, in the presence of CO and HCOOH, is an efficient catalytic system for the regioselective conversion of alkenes into branched and linear aldehydes. This process shows excellent functional group tolerance.

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KW - Aldehydes

KW - Alkene conversion

KW - Carbon monoxide

KW - Formic acid

KW - Regioselectivity

KW - Rhodium

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