A novel polymeric Cd[SSe2N2] central core five-coordinate complex: Synthesis, X-ray structure and 113Cd, 77Se CP MAS NMR characterization of catena(bis(μ2-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II))

Mohammed Fettouhi; Mohammed I.M. Wazeer; Anvarhusein A. Isab

doi:10.1016/j.inoche.2007.11.005

A novel polymeric Cd[SSe₂N₂] central core five-coordinate complex: Synthesis, X-ray structure and ¹¹³Cd, ⁷⁷Se CP MAS NMR characterization of catena(bis(μ₂-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II))

Mohammed Fettouhi, Mohammed I.M. Wazeer, Anvarhusein A. Isab^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Cadmium(II) selenocyanate reacts with N,N′-dimethylimidazolidine-2-thione (Me₂Imt) at a 1:1 ratio forming a polymeric [(Me₂Imt)Cd(SeCN)₂]_∞ complex. The metal ion is bonded to one imidazolidine thione through the sulfur atom, two selenocyanate ions through their selenium atoms and two other selenocyanates through their nitrogen atoms. The metal complex coordination sphere Cd[SSe₂N₂] adopts a distorted trigonal bipyramidal geometry with the chalcogen atoms occupying the equatorial positions and the nitrogen atoms in the axial positions. The ⁷⁷Se CP MAS NMR data are consistent with two different selenium sites and the shielding tensor parameters of ¹¹³Cd point to a near axial symmetry for the cadmium environment.

Original language	English
Pages (from-to)	252-255
Number of pages	4
Journal	Inorganic Chemistry Communication
Volume	11
Issue number	3
DOIs	https://doi.org/10.1016/j.inoche.2007.11.005
State	Published - Mar 2008

Bibliographical note

Funding Information:
This research was supported by the KFUPM Research Committee under project number SABIC (SB070010).

Keywords

Cadmium selenocyanate
Cd
N,N′-Dimethylimidazolidine-2-thione
Se CP MAS NMR
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.inoche.2007.11.005

Fingerprint

Dive into the research topics of 'A novel polymeric Cd[SSe₂N₂] central core five-coordinate complex: Synthesis, X-ray structure and ¹¹³Cd, ⁷⁷Se CP MAS NMR characterization of catena(bis(μ₂-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II))'. Together they form a unique fingerprint.

Cite this

Fettouhi, M., Wazeer, M. I. M., & Isab, A. A. (2008). A novel polymeric Cd[SSe₂N₂] central core five-coordinate complex: Synthesis, X-ray structure and ¹¹³Cd, ⁷⁷Se CP MAS NMR characterization of catena(bis(μ₂-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II)). Inorganic Chemistry Communication, 11(3), 252-255. https://doi.org/10.1016/j.inoche.2007.11.005

Fettouhi, Mohammed ; Wazeer, Mohammed I.M. ; Isab, Anvarhusein A. / A novel polymeric Cd[SSe₂N₂] central core five-coordinate complex : Synthesis, X-ray structure and ¹¹³Cd, ⁷⁷Se CP MAS NMR characterization of catena(bis(μ₂-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II)). In: Inorganic Chemistry Communication. 2008 ; Vol. 11, No. 3. pp. 252-255.

@article{ca355d2bd59d4935b297260710f4bab9,

title = "A novel polymeric Cd[SSe2N2] central core five-coordinate complex: Synthesis, X-ray structure and 113Cd, 77Se CP MAS NMR characterization of catena(bis(μ2-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II))",

abstract = "Cadmium(II) selenocyanate reacts with N,N′-dimethylimidazolidine-2-thione (Me2Imt) at a 1:1 ratio forming a polymeric [(Me2Imt)Cd(SeCN)2]∞ complex. The metal ion is bonded to one imidazolidine thione through the sulfur atom, two selenocyanate ions through their selenium atoms and two other selenocyanates through their nitrogen atoms. The metal complex coordination sphere Cd[SSe2N2] adopts a distorted trigonal bipyramidal geometry with the chalcogen atoms occupying the equatorial positions and the nitrogen atoms in the axial positions. The 77Se CP MAS NMR data are consistent with two different selenium sites and the shielding tensor parameters of 113Cd point to a near axial symmetry for the cadmium environment.",

keywords = "Cadmium selenocyanate, Cd, N,N′-Dimethylimidazolidine-2-thione, Se CP MAS NMR, X-ray structure",

author = "Mohammed Fettouhi and Wazeer, \{Mohammed I.M.\} and Isab, \{Anvarhusein A.\}",

note = "Funding Information: This research was supported by the KFUPM Research Committee under project number SABIC (SB070010).",

year = "2008",

month = mar,

doi = "10.1016/j.inoche.2007.11.005",

language = "English",

volume = "11",

pages = "252--255",

journal = "Inorganic Chemistry Communication",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "3",

}

Fettouhi, M, Wazeer, MIM & Isab, AA 2008, 'A novel polymeric Cd[SSe₂N₂] central core five-coordinate complex: Synthesis, X-ray structure and ¹¹³Cd, ⁷⁷Se CP MAS NMR characterization of catena(bis(μ₂-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II))', Inorganic Chemistry Communication, vol. 11, no. 3, pp. 252-255. https://doi.org/10.1016/j.inoche.2007.11.005

A novel polymeric Cd[SSe₂N₂] central core five-coordinate complex: Synthesis, X-ray structure and ¹¹³Cd, ⁷⁷Se CP MAS NMR characterization of catena(bis(μ₂-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II)). / Fettouhi, Mohammed; Wazeer, Mohammed I.M.; Isab, Anvarhusein A.
In: Inorganic Chemistry Communication, Vol. 11, No. 3, 03.2008, p. 252-255.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A novel polymeric Cd[SSe2N2] central core five-coordinate complex

T2 - Synthesis, X-ray structure and 113Cd, 77Se CP MAS NMR characterization of catena(bis(μ2-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II))

AU - Fettouhi, Mohammed

AU - Wazeer, Mohammed I.M.

AU - Isab, Anvarhusein A.

N1 - Funding Information: This research was supported by the KFUPM Research Committee under project number SABIC (SB070010).

PY - 2008/3

Y1 - 2008/3

N2 - Cadmium(II) selenocyanate reacts with N,N′-dimethylimidazolidine-2-thione (Me2Imt) at a 1:1 ratio forming a polymeric [(Me2Imt)Cd(SeCN)2]∞ complex. The metal ion is bonded to one imidazolidine thione through the sulfur atom, two selenocyanate ions through their selenium atoms and two other selenocyanates through their nitrogen atoms. The metal complex coordination sphere Cd[SSe2N2] adopts a distorted trigonal bipyramidal geometry with the chalcogen atoms occupying the equatorial positions and the nitrogen atoms in the axial positions. The 77Se CP MAS NMR data are consistent with two different selenium sites and the shielding tensor parameters of 113Cd point to a near axial symmetry for the cadmium environment.

AB - Cadmium(II) selenocyanate reacts with N,N′-dimethylimidazolidine-2-thione (Me2Imt) at a 1:1 ratio forming a polymeric [(Me2Imt)Cd(SeCN)2]∞ complex. The metal ion is bonded to one imidazolidine thione through the sulfur atom, two selenocyanate ions through their selenium atoms and two other selenocyanates through their nitrogen atoms. The metal complex coordination sphere Cd[SSe2N2] adopts a distorted trigonal bipyramidal geometry with the chalcogen atoms occupying the equatorial positions and the nitrogen atoms in the axial positions. The 77Se CP MAS NMR data are consistent with two different selenium sites and the shielding tensor parameters of 113Cd point to a near axial symmetry for the cadmium environment.

KW - Cadmium selenocyanate

KW - Cd

KW - N,N′-Dimethylimidazolidine-2-thione

KW - Se CP MAS NMR

KW - X-ray structure

UR - https://www.scopus.com/pages/publications/39649113541

U2 - 10.1016/j.inoche.2007.11.005

DO - 10.1016/j.inoche.2007.11.005

M3 - Article

AN - SCOPUS:39649113541

SN - 1387-7003

VL - 11

SP - 252

EP - 255

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

IS - 3

ER -