A multiconfigurational analysis of the 3d spectra of Rb I and Sr I

M. W.D. Mansfield; J. P. Connerade

doi:10.1088/0022-3700/15/4/003

A multiconfigurational analysis of the 3d spectra of Rb I and Sr I

M. W.D. Mansfield^*, J. P. Connerade

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The results of HXR calculations of the 3d subshell absorption spectra of Rb I and Sr I are presented. Both the transition energies and their intensities are compared with experiment and the resulting assignments of the experimental peaks are discussed in relation to those obtained by self-consistent field calculations and by the Z+1 approximation. The limitations in the applicability of the Z+1 model in cases where strong s-d mixing is induced by wavefunction collapse are indicated.

Original language	English
Article number	003
Pages (from-to)	503-512
Number of pages	10
Journal	Journal of Physics B: Atomic and Molecular Physics
Volume	15
Issue number	4
DOIs	https://doi.org/10.1088/0022-3700/15/4/003
State	Published - 1982

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics

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title = "A multiconfigurational analysis of the 3d spectra of Rb I and Sr I",

abstract = "The results of HXR calculations of the 3d subshell absorption spectra of Rb I and Sr I are presented. Both the transition energies and their intensities are compared with experiment and the resulting assignments of the experimental peaks are discussed in relation to those obtained by self-consistent field calculations and by the Z+1 approximation. The limitations in the applicability of the Z+1 model in cases where strong s-d mixing is induced by wavefunction collapse are indicated.",

author = "Mansfield, {M. W.D.} and Connerade, {J. P.}",

year = "1982",

doi = "10.1088/0022-3700/15/4/003",

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AU - Mansfield, M. W.D.

AU - Connerade, J. P.

PY - 1982

Y1 - 1982

N2 - The results of HXR calculations of the 3d subshell absorption spectra of Rb I and Sr I are presented. Both the transition energies and their intensities are compared with experiment and the resulting assignments of the experimental peaks are discussed in relation to those obtained by self-consistent field calculations and by the Z+1 approximation. The limitations in the applicability of the Z+1 model in cases where strong s-d mixing is induced by wavefunction collapse are indicated.

AB - The results of HXR calculations of the 3d subshell absorption spectra of Rb I and Sr I are presented. Both the transition energies and their intensities are compared with experiment and the resulting assignments of the experimental peaks are discussed in relation to those obtained by self-consistent field calculations and by the Z+1 approximation. The limitations in the applicability of the Z+1 model in cases where strong s-d mixing is induced by wavefunction collapse are indicated.

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U2 - 10.1088/0022-3700/15/4/003

DO - 10.1088/0022-3700/15/4/003

M3 - Article

AN - SCOPUS:0000960834

SN - 0022-3700

VL - 15

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JO - Journal of Physics B: Atomic and Molecular Physics

JF - Journal of Physics B: Atomic and Molecular Physics

IS - 4

M1 - 003

ER -

A multiconfigurational analysis of the 3d spectra of Rb I and Sr I

Abstract

ASJC Scopus subject areas

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