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“A Lot’s in a Name”: Insights from Debates on Thermal and Nonthermal Effects in Plasmonic Catalysis

Research output: Contribution to journalReview articlepeer-review

8 Scopus citations

Abstract

Plasmonic catalysis is uniquely positioned between photochemistry/electrochemistry and thermal chemistry such that multiple factors may compete to dominate the reaction enhancement mechanism. The adoption of norms originating in both photochemistry and thermal chemistry has resulted in the use of language and methods of data analysis, which, in the context of plasmonic catalysis, may be implicitly contradictory. This article tracks several years of research toward understanding thermal and nonthermal effects in plasmonic catalysis and culminates with a discussion on how the choice of language and presentation of data can be tuned to avoid subtle yet significant contradictory implications.

Original languageEnglish
Pages (from-to)11762-11772
Number of pages11
JournalACS Applied Energy Materials
Volume6
Issue number23
DOIs
StatePublished - 11 Dec 2023

Bibliographical note

Publisher Copyright:
© 2023 American Chemical Society.

Keywords

  • heterogeneous catalysis
  • light penetration
  • photochemistry
  • photothermal effect
  • plasmonic catalysis
  • quantum efficiency
  • thermal gradient

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Energy Engineering and Power Technology
  • Electrochemistry
  • Materials Chemistry
  • Electrical and Electronic Engineering

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