A highly selective fluorescent turn-on probe for Al3+ via Al3+-promoted hydrolysis of ester

Aasif Helal; Sang Hyun Kim; Hong Seok Kim

doi:10.1016/j.tet.2013.05.062

A highly selective fluorescent turn-on probe for Al³⁺ via Al³⁺-promoted hydrolysis of ester

Aasif Helal, Sang Hyun Kim, Hong Seok Kim^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

A new reactive and highly selective fluorescent chemosensor (1) based on thiazole was synthesized for the quantification of aluminum ions in ethanol. The mechanism of fluorescence was based on the aluminum-promoted hydrolysis of the ester moiety and subsequent complexation.

Original language	English
Pages (from-to)	6095-6099
Number of pages	5
Journal	Tetrahedron
Volume	69
Issue number	30
DOIs	https://doi.org/10.1016/j.tet.2013.05.062
State	Published - 29 Jul 2013
Externally published	Yes

Bibliographical note

Funding Information:
This research was supported by the NRF grant funded by MEST in Korea ( NRF-2010-0010070 ).

Keywords

Al- promoted
Al-selective
Fluorescent probe
Hydrolysis
Turn-on

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tet.2013.05.062

Cite this

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title = "A highly selective fluorescent turn-on probe for Al3+ via Al3+-promoted hydrolysis of ester",

abstract = "A new reactive and highly selective fluorescent chemosensor (1) based on thiazole was synthesized for the quantification of aluminum ions in ethanol. The mechanism of fluorescence was based on the aluminum-promoted hydrolysis of the ester moiety and subsequent complexation.",

keywords = "Al- promoted, Al-selective, Fluorescent probe, Hydrolysis, Turn-on",

author = "Aasif Helal and Kim, \{Sang Hyun\} and Kim, \{Hong Seok\}",

note = "Funding Information: This research was supported by the NRF grant funded by MEST in Korea ( NRF-2010-0010070 ). ",

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AU - Helal, Aasif

AU - Kim, Sang Hyun

AU - Kim, Hong Seok

N1 - Funding Information: This research was supported by the NRF grant funded by MEST in Korea ( NRF-2010-0010070 ).

PY - 2013/7/29

Y1 - 2013/7/29

N2 - A new reactive and highly selective fluorescent chemosensor (1) based on thiazole was synthesized for the quantification of aluminum ions in ethanol. The mechanism of fluorescence was based on the aluminum-promoted hydrolysis of the ester moiety and subsequent complexation.

AB - A new reactive and highly selective fluorescent chemosensor (1) based on thiazole was synthesized for the quantification of aluminum ions in ethanol. The mechanism of fluorescence was based on the aluminum-promoted hydrolysis of the ester moiety and subsequent complexation.

KW - Al- promoted

KW - Al-selective

KW - Fluorescent probe

KW - Hydrolysis

KW - Turn-on

UR - https://www.scopus.com/pages/publications/84878930960

U2 - 10.1016/j.tet.2013.05.062

DO - 10.1016/j.tet.2013.05.062

M3 - Article

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SN - 0040-4020

VL - 69

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EP - 6099

JO - Tetrahedron

JF - Tetrahedron

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