A convenient palladium-catalyzed carbonylative synthesis of 2-aminbenzoxazinones from 2-bromoanilines and isocyanates

Xiao Feng Wu; Muhammad Sharif; Khurram Shoaib; Helfried Neumann; Anahit Pews-Davtyan; Peter Langer; Matthias Beller

doi:10.1002/chem.201300537

A convenient palladium-catalyzed carbonylative synthesis of 2-aminbenzoxazinones from 2-bromoanilines and isocyanates

Xiao Feng Wu^*
, Muhammad Sharif
, Khurram Shoaib
, Helfried Neumann
, Anahit Pews-Davtyan
, Peter Langer
, Matthias Beller

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

Mon ami(ne)! A general and convenient methodology for 2-aminobenzoxazinone synthesis has been developed (see scheme). Readily available 2-bromoanilines and isocyanates were used as substrates and various products have been prepared in good yields. Notably, [Mo(CO)₆] as a solid CO source was applied instead of gas.

Original language	English
Pages (from-to)	6230-6233
Number of pages	4
Journal	Chemistry - A European Journal
Volume	19
Issue number	20
DOIs	https://doi.org/10.1002/chem.201300537
State	Published - 10 May 2013
Externally published	Yes

Keywords

benzoxazinones
carbonylation
catalysis
nitrogen heterocycles
palladium

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201300537

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title = "A convenient palladium-catalyzed carbonylative synthesis of 2-aminbenzoxazinones from 2-bromoanilines and isocyanates",

abstract = "Mon ami(ne)! A general and convenient methodology for 2-aminobenzoxazinone synthesis has been developed (see scheme). Readily available 2-bromoanilines and isocyanates were used as substrates and various products have been prepared in good yields. Notably, [Mo(CO)6] as a solid CO source was applied instead of gas.",

keywords = "benzoxazinones, carbonylation, catalysis, nitrogen heterocycles, palladium",

author = "Wu, \{Xiao Feng\} and Muhammad Sharif and Khurram Shoaib and Helfried Neumann and Anahit Pews-Davtyan and Peter Langer and Matthias Beller",

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T1 - A convenient palladium-catalyzed carbonylative synthesis of 2-aminbenzoxazinones from 2-bromoanilines and isocyanates

AU - Wu, Xiao Feng

AU - Sharif, Muhammad

AU - Shoaib, Khurram

AU - Neumann, Helfried

AU - Pews-Davtyan, Anahit

AU - Langer, Peter

AU - Beller, Matthias

PY - 2013/5/10

Y1 - 2013/5/10

N2 - Mon ami(ne)! A general and convenient methodology for 2-aminobenzoxazinone synthesis has been developed (see scheme). Readily available 2-bromoanilines and isocyanates were used as substrates and various products have been prepared in good yields. Notably, [Mo(CO)6] as a solid CO source was applied instead of gas.

AB - Mon ami(ne)! A general and convenient methodology for 2-aminobenzoxazinone synthesis has been developed (see scheme). Readily available 2-bromoanilines and isocyanates were used as substrates and various products have been prepared in good yields. Notably, [Mo(CO)6] as a solid CO source was applied instead of gas.

KW - benzoxazinones

KW - carbonylation

KW - catalysis

KW - nitrogen heterocycles

KW - palladium

UR - https://www.scopus.com/pages/publications/84877309207

U2 - 10.1002/chem.201300537

DO - 10.1002/chem.201300537

M3 - Article

C2 - 23519727

AN - SCOPUS:84877309207

SN - 0947-6539

VL - 19

SP - 6230

EP - 6233

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 20

ER -

A convenient palladium-catalyzed carbonylative synthesis of 2-aminbenzoxazinones from 2-bromoanilines and isocyanates

Abstract

Keywords

ASJC Scopus subject areas

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