8–Hydroxyquinoline is key to the development of corrosion inhibitors: An advanced review

  • Elyor Berdimurodov*
  • , Chandrabhan Verma
  • , Khasan Berdimuradov
  • , M. A. Quraishi
  • , Abduvali Kholikov
  • , Khamdam Akbarov
  • , Nurbek Umirov
  • , Bakhtiyor Borikhonov
  • *Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

62 Scopus citations

Abstract

8–Hydroxyquinoline (8–HQ) is known for its strong coordination and chelation behaviours. Because of this, 8–HQ and its derivatives manifest exceptionally high potential for corrosion inhibition. Using the nonbonding electrons of oxygen and nitrogen, 8–HQ and its derivatives coordinate strongly with metallic surfaces, which results in strong inhibition of corrosion. The current assessment considers a collection of reports on the corrosion inhibition potentials of 8–HQ and its derivatives. 8–HQ and its derivatives become effectual by adsorbing on the metal surface, and the adsorption mode is physiochemisorption. Corrosion inhibition by HQ derivatives is highly dependent on the natures of the functional groups. Literature studies have specified that 8–HQ and its derivatives serve as mixed–type inhibitors that retard both anodic and cathodic Tafel reactions. Moreover, after adsorption, 8–HQ and its derivatives build layers between metal surfaces and electrolytes that behave as barriers to charge transfer processes. Adsorption mainly follows the Langmuir adsorption isotherm. The results of literature studies indicate that 8–HQ derivatives bind with metal surfaces via charge transfer processes, achieve flat alignment and deliver high superficial coverage. This review will be important in developing a new generation of corrosion inhibitors based on 8–HQ and its derivatives.

Original languageEnglish
Article number109839
JournalInorganic Chemistry Communication
Volume144
DOIs
StatePublished - Oct 2022

Bibliographical note

Publisher Copyright:
© 2022 Elsevier B.V.

Keywords

  • 8–Hydroxyquinoline
  • Adsorption
  • Carbon steels
  • Chelation
  • Coordination bonding
  • Corrosion inhibitors
  • Corrosion protection

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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