μ-2,2′-Bipyrimidine-κ4N1,N 1′:N3,N3′- bis[iodido(triphenylphosphane-κP)copper(I)] dimethylformamide disolvate

Mohammed Fettouhi

doi:10.1107/S1600536812028139

μ-2,2′-Bipyrimidine-κ⁴N¹,N ^1′:N³,N^3′- bis[iodido(triphenylphosphane-κP)copper(I)] dimethylformamide disolvate

Mohammed Fettouhi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In the title binuclear centrosymmetric complex, [Cu₂I ₂(C₈H₆N₄)(C₁₈H ₁₅P)₂]·2C₃H₇NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenylphosphane ligand in a distorted tetrahedral N₂IP geometry. The complex molecules pack in columns parallel to [100] generating cavities occupied by dimethylformamide solvent molecules. Weak C - H⋯I hydrogen-bonding interactions help to stabilize the crystal packing.

Original language	English
Pages (from-to)	m1003
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	7
DOIs	https://doi.org/10.1107/S1600536812028139
State	Published - Jul 2012

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536812028139

Cite this

@article{74c563ef92de4a36956c0888f68d5731,

title = "μ-2,2′-Bipyrimidine-κ4N1,N 1′:N3,N3′- bis[iodido(triphenylphosphane-κP)copper(I)] dimethylformamide disolvate",

abstract = "In the title binuclear centrosymmetric complex, [Cu2I 2(C8H6N4)(C18H 15P)2]·2C3H7NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenylphosphane ligand in a distorted tetrahedral N2IP geometry. The complex molecules pack in columns parallel to [100] generating cavities occupied by dimethylformamide solvent molecules. Weak C - H⋯I hydrogen-bonding interactions help to stabilize the crystal packing.",

author = "Mohammed Fettouhi",

year = "2012",

month = jul,

doi = "10.1107/S1600536812028139",

language = "English",

volume = "68",

pages = "m1003",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

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T1 - μ-2,2′-Bipyrimidine-κ4N1,N 1′:N3,N3′- bis[iodido(triphenylphosphane-κP)copper(I)] dimethylformamide disolvate

AU - Fettouhi, Mohammed

PY - 2012/7

Y1 - 2012/7

N2 - In the title binuclear centrosymmetric complex, [Cu2I 2(C8H6N4)(C18H 15P)2]·2C3H7NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenylphosphane ligand in a distorted tetrahedral N2IP geometry. The complex molecules pack in columns parallel to [100] generating cavities occupied by dimethylformamide solvent molecules. Weak C - H⋯I hydrogen-bonding interactions help to stabilize the crystal packing.

AB - In the title binuclear centrosymmetric complex, [Cu2I 2(C8H6N4)(C18H 15P)2]·2C3H7NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenylphosphane ligand in a distorted tetrahedral N2IP geometry. The complex molecules pack in columns parallel to [100] generating cavities occupied by dimethylformamide solvent molecules. Weak C - H⋯I hydrogen-bonding interactions help to stabilize the crystal packing.

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U2 - 10.1107/S1600536812028139

DO - 10.1107/S1600536812028139

M3 - Article

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SP - m1003

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7